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<h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Perfluoroctan</span></h1>
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<div id="mw-content-text" class="mw-body-content mw-content-ltr" lang="de" dir="ltr"><div class="mw-content-ltr mw-parser-output" lang="de" dir="ltr"><table class="wikitable infobox float-right" id="Vorlage_Infobox_Chemikalie" style="font-size:90%; margin-top:0; width:350px;" summary="Infobox Chemikalie">
<tbody><tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Strukturformel
</th></tr>
<tr>
<td colspan="2" class="hintergrundfarbe-basis skin-invert-image" style="text-align:center;"><span class="mw-default-size" typeof="mw:File"></span>
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<th colspan="2" style="background:#FFDEAD; color:#202122;">Allgemeines
</th></tr>
<tr>
<td style="width:33%;">Name
</td>
<td>Perfluoroctan
</td></tr>
<tr>
<td>Andere Namen
</td>
<td>
<ul><li>Octadecafluoroctan</li>
<li>1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Octadecafluoroctan</li>
<li>PF5080</li></ul>
</td></tr>
<tr>
<td><a href="Summenformel" title="Summenformel">Summenformel</a>
</td>
<td>C<sub>8</sub>F<sub>18</sub>
</td></tr>
<tr>
<td>Kurzbeschreibung
</td>
<td>
<p>farblose bis gelbliche Flüssigkeit<sup id="cite_ref-Sigma_1-0" class="reference"><a href="#cite_note-Sigma-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Externe Identifikatoren/Datenbanken
</th></tr>
<tr>
<td colspan="2" style="padding:0;">
<table class="mw-collapsible mw-collapsed wikitable" data-expandtext="+" data-collapsetext="−" style="border-top:none; margin:-1px; width:calc(100% + 2px);">
<tbody><tr>
<td style="width:33%;"><a href="CAS-Nummer" title="CAS-Nummer">CAS-Nummer</a>
</td>
<td><span title="Untervorlage eingebunden: CASRN"></span><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=307-34-6">307-34-6</a><span class="editoronly" style="display:none;"></span>
</td>
<td style="background:#FFDEAD; color:#202122; border-top:1px solid #FFDEAD; padding:0.2em 0; vertical-align:bottom; width:5%;">
</td></tr>
<tr>
<td><a href="EG-Nummer" title="EG-Nummer">EG-Nummer</a>
</td>
<td colspan="2">206-199-2
</td></tr>
<tr>
<td><a href="Europ%C3%A4ische_Chemikalienagentur" title="Europäische Chemikalienagentur">ECHA</a>-InfoCard
</td>
<td colspan="2"><a rel="nofollow" class="external text" href="https://www.echa.europa.eu/de/substance-information/-/substanceinfo/100.005.637">100.005.637</a>
</td></tr>
<tr>
<td><a href="PubChem" title="PubChem">PubChem</a>
</td>
<td colspan="2"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/9387">9387</a>
</td></tr>
<tr>
<td><a href="DrugBank" title="DrugBank">DrugBank</a>
</td>
<td colspan="2"><a rel="nofollow" class="external text" href="https://www.drugbank.ca/drugs/DB15997">DB15997</a>
</td></tr>
<tr>
<td style="border-right:1px solid #a2a9b1;"><a href="Wikidata" title="Wikidata">Wikidata</a>
</td>
<td colspan="2"><a href="https://www.wikidata.org/wiki/Q421426" class="extiw external" title="d:Q421426">Q421426</a>
</td></tr></tbody></table>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Eigenschaften
</th></tr>
<tr>
<td><a href="Molare_Masse" title="Molare Masse">Molare Masse</a>
</td>
<td>438,06 g·<a href="Mol" title="Mol">mol</a><sup>−1</sup>
</td></tr>
<tr>
<td><a href="Aggregatzustand" title="Aggregatzustand">Aggregatzustand</a>
</td>
<td>
<p>flüssig<sup id="cite_ref-Sigma_1-1" class="reference"><a href="#cite_note-Sigma-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td><a href="Dichte" title="Dichte">Dichte</a>
</td>
<td>
<p>1,766 g·cm<sup>−3</sup> (25 °C)<sup id="cite_ref-Sigma_1-2" class="reference"><a href="#cite_note-Sigma-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td><a href="Schmelzpunkt" title="Schmelzpunkt">Schmelzpunkt</a>
</td>
<td>
<p>−25 <a href="Grad_Celsius" title="Grad Celsius">°C</a><sup id="cite_ref-Sigma_1-3" class="reference"><a href="#cite_note-Sigma-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td><a href="Siedepunkt" title="Siedepunkt">Siedepunkt</a>
</td>
<td>
<p>103–104 °C<sup id="cite_ref-Sigma_1-4" class="reference"><a href="#cite_note-Sigma-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td><a href="L%C3%B6slichkeit" title="Löslichkeit">Löslichkeit</a>
</td>
<td>
<p>nahezu unlöslich in Wasser<sup id="cite_ref-Sigma_1-5" class="reference"><a href="#cite_note-Sigma-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td><a href="Brechungsindex" title="Brechungsindex">Brechungsindex</a>
</td>
<td>
<p>1,282 (20 °C)<sup id="cite_ref-CRC90_3_420_2-0" class="reference"><a href="#cite_note-CRC90_3_420-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Sicherheitshinweise
</th></tr>
<tr>
<td colspan="2">
<table cellspacing="0" cellpadding="2" style="width:100%;">
<tbody><tr>
<td colspan="2" style="text-align:center"><b><a href="Global_harmonisiertes_System_zur_Einstufung_und_Kennzeichnung_von_Chemikalien" title="Global harmonisiertes System zur Einstufung und Kennzeichnung von Chemikalien">GHS-Gefahrstoffkennzeichnung</a></b><sup id="cite_ref-Sigma_1-6" class="reference"><a href="#cite_note-Sigma-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
<table class="hintergrundfarbe-neutral" style="text-align:center; margin-left:auto; margin-right:auto; display:flex; justify-content:center;">
<tbody><tr>
<td><i>keine GHS-Piktogramme</i>
</td></tr></tbody></table>
<p>
</p>
</td></tr>
<tr>
<td rowspan="2" width="33%" style="border-top:1px #A7A7A7 dashed; border-right:1px #A7A7A7 dashed;"><a href="H-_und_P-S%C3%A4tze" title="H- und P-Sätze">H- und P-Sätze</a>
</td>
<td style="border-top:1px #A7A7A7 dashed;">H: <span title="Untervorlage eingebunden: H-Sätze"></span><i>keine H-Sätze</i>
</td></tr>
<tr>
<td style="border-top:1px #A7A7A7 dashed;">P: <span title="Untervorlage eingebunden: P-Sätze"></span><i>keine P-Sätze</i>
</td></tr>
</tbody></table>
</td></tr>
<tr>
<td><a href="Treibhauspotential" title="Treibhauspotential">Treibhauspotential</a>
</td>
<td>
<p>8456 (bezogen auf 100 Jahre)<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td colspan="2" style="background:#FFDEAD; color:#202122; font-size:80%; text-align:center; line-height:150%; padding:.25em;">Wenn nicht anders vermerkt, gelten die angegebenen Daten bei <a href="Standardbedingungen" title="Standardbedingungen">Standardbedingungen</a> (0 °C, 1000 hPa). Brechungsindex: <a href="Natrium-D-Linie" title="Natrium-D-Linie">Na-D-Linie</a>, 20 °C
</td></tr></tbody></table><p><span class="editoronly" style="display:none;"></span>
</p><p><b>Perfluoroctan</b> ist eine <a href="Chemische_Verbindung" title="Chemische Verbindung">chemische Verbindung</a> aus der Gruppe der <a href="Perfluorcarbone" title="Perfluorcarbone">Perfluorcarbone</a>.
</p>
<div class="mw-heading mw-heading2"><h2 id="Eigenschaften">Eigenschaften</h2></div>
<p>Perfluoroctan ist eine farblose bis gelbliche Flüssigkeit, die unlöslich in Wasser ist.<sup id="cite_ref-Sigma_1-7" class="reference"><a href="#cite_note-Sigma-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Verwendung">Verwendung</h2></div>
<p>Perfluoroctan wird (wie auch <a href="Perflunafen" title="Perflunafen">Perfluordecalin</a>) bei der operativen Behandlung einer <a href="Netzhautabl%C3%B6sung" title="Netzhautablösung">Netzhautablösung</a> am Auge als mechanisches Hilfsmittel, um die <a href="Netzhaut" title="Netzhaut">Netzhaut</a> faltenfrei an den Augapfel anzudrücken, verwendet.<sup id="cite_ref-Günter_Fred_Fuhrmann_4-0" class="reference"><a href="#cite_note-Günter_Fred_Fuhrmann-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>
</p><p>Laut Angaben der chemischen Industrie handelt es sich bei Perfluoroctan um eine von 256 <a href="Per-_und_polyfluorierte_Alkylverbindungen" title="Per- und polyfluorierte Alkylverbindungen">PFAS</a> mit kommerzieller Relevanz<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> aus der <a href="OECD" class="mw-redirect" title="OECD">OECD</a>-Liste von 4730 PFAS.<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Analytik">Analytik</h2></div>
<p>Perfluoroctan kann mittels <a href="Massenspektrometrie" title="Massenspektrometrie">Massenspektrometrie</a> nachgewiesen werden. Als <a href="Ionisierung" class="mw-redirect" title="Ionisierung">Ionisierung</a> eignen sich hierbei plasmabasierende Methoden, wie <a href="APCI" class="mw-redirect" title="APCI">APCI</a> oder <a href="Stille_elektrische_Entladung" title="Stille elektrische Entladung">DBDI</a>.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Einzelnachweise">Einzelnachweise</h2></div>
<ol class="references">
<li id="cite_note-Sigma-1"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-Sigma_1-0">a</a></sup> <sup><a href="#cite_ref-Sigma_1-1">b</a></sup> <sup><a href="#cite_ref-Sigma_1-2">c</a></sup> <sup><a href="#cite_ref-Sigma_1-3">d</a></sup> <sup><a href="#cite_ref-Sigma_1-4">e</a></sup> <sup><a href="#cite_ref-Sigma_1-5">f</a></sup> <sup><a href="#cite_ref-Sigma_1-6">g</a></sup> <sup><a href="#cite_ref-Sigma_1-7">h</a></sup></span> <span class="reference-text">Datenblatt <span style="font-style:italic;"><a rel="nofollow" class="external text" href="https://www.sigmaaldrich.com/catalog/product/ALDRICH/359238">Perfluoroctan, 98%</a></span> bei <a href="Sigma-Aldrich" title="Sigma-Aldrich">Sigma-Aldrich</a>, abgerufen am 10. November 2012 (<a rel="nofollow" class="external text" href="https://www.sigmaaldrich.com/DE/de/sds/ALDRICH/359238?userType=anonymous">PDF</a>).<span class="editoronly" style="display:none;"></span></span>
</li>
<li id="cite_note-CRC90_3_420-2"><span class="mw-cite-backlink"><a href="#cite_ref-CRC90_3_420_2-0">↑</a></span> <span class="reference-text">David R. Lide (Hrsg.): <i><a href="CRC_Handbook_of_Chemistry_and_Physics" title="CRC Handbook of Chemistry and Physics">CRC Handbook of Chemistry and Physics</a></i>. 90. Auflage. (Internet-Version: 2010), CRC Press / Taylor and Francis, Boca Raton FL, <i>Physical Constants of Organic Compounds</i>, S. 3-420.<span class="editoronly" style="display:none;"></span></span>
</li>
<li id="cite_note-3"><span class="mw-cite-backlink"><a href="#cite_ref-3">↑</a></span> <span class="reference-text">G. Myhre, D. Shindell et al.: <cite style="font-style:italic">Climate Change 2013: The Physical Science Basis</cite>. Working Group I contribution to the IPCC Fifth Assessment Report. Hrsg.: <a href="Intergovernmental_Panel_on_Climate_Change" title="Intergovernmental Panel on Climate Change">Intergovernmental Panel on Climate Change</a>. 2013, Chapter 8: Anthropogenic and Natural Radiative Forcing, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>24–39; Table 8.SM.16</span> (<a rel="nofollow" class="external text" href="https://www.ipcc.ch/site/assets/uploads/2018/07/WGI_AR5.Chap_.8_SM.pdf">PDF</a>).<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abookitem&rfr_id=info:sid/de.wikipedia.org:Perfluoroctan&rft.atitle=Chapter+8%3A+Anthropogenic+and+Natural+Radiative+Forcing&rft.au=G.+Myhre%2C+D.+Shindell+et+al.&rft.btitle=Climate+Change+2013%3A+The+Physical+Science+Basis&rft.date=2013&rft.genre=bookitem&rft.pages=24-39%3B+Table+8.SM.16" style="display:none"> </span></span>
</li>
<li id="cite_note-Günter_Fred_Fuhrmann-4"><span class="mw-cite-backlink"><a href="#cite_ref-Günter_Fred_Fuhrmann_4-0">↑</a></span> <span class="reference-text">Günter Fred Fuhrmann: <cite style="font-style:italic">Toxikologie für Naturwissenschaftler: Einführung in die Theoretische und Spezielle Toxikologie</cite>. Springer, 2006, ISBN 3-8351-0024-6, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>345</span> (<a rel="nofollow" class="external text" href="https://books.google.de/books?id=XZgHk4yelkoC&pg=PA345#v=onepage">eingeschränkte Vorschau</a> in der Google-Buchsuche).<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rfr_id=info:sid/de.wikipedia.org:Perfluoroctan&rft.au=G%C3%BCnter+Fred+Fuhrmann&rft.btitle=Toxikologie+f%C3%BCr+Naturwissenschaftler%3A+Einf%C3%BChrung+in+die+Theoretische+und+Spezielle+Toxikologie&rft.date=2006&rft.genre=book&rft.isbn=3835100246&rft.pages=345&rft.pub=Springer" style="display:none"> </span></span>
</li>
<li id="cite_note-5"><span class="mw-cite-backlink"><a href="#cite_ref-5">↑</a></span> <span class="reference-text">Robert C. Buck, Stephen H. Korzeniowski, Evan Laganis, Frank Adamsky: <cite style="font-style:italic">Identification and classification of commercially relevant per‐ and poly‐fluoroalkyl substances (PFAS)</cite>. In: <cite style="font-style:italic"><a href="Integrated_Environmental_Assessment_and_Management" title="Integrated Environmental Assessment and Management">Integrated Environmental Assessment and Management</a></cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em"> </span>17</span>, <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em"> </span>5</span>, 2021, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>1045–1055</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1002/ieam.4450">10.1002/ieam.4450</a></span>, <a class="external mw-magiclink-pmid" rel="nofollow" href="https://www.ncbi.nlm.nih.gov/pubmed/33991049?dopt=Abstract">PMID 33991049</a>, <a rel="nofollow" class="external text" href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9292543/">PMC 9292543</a> (freier Volltext).<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rfr_id=info:sid/de.wikipedia.org:Perfluoroctan&rft.atitle=Identification+and+classification+of+commercially+relevant+per%E2%80%90+and+poly%E2%80%90fluoroalkyl+substances+%28PFAS%29&rft.au=Robert+C.+Buck%2C+Stephen+H.+Korzeniowski%2C+Evan+Laganis%2C+...&rft.date=2021&rft.doi=10.1002%2Fieam.4450&rft.genre=journal&rft.issue=5&rft.jtitle=Integrated+Environmental+Assessment+and+Management&rft.pages=1045-1055&rft.pmc=9292543&rft.pmid=33991049&rft.volume=17" style="display:none"> </span></span>
</li>
<li id="cite_note-6"><span class="mw-cite-backlink"><a href="#cite_ref-6">↑</a></span> <span class="reference-text"><span class="cite"><a rel="nofollow" class="external text" href="https://cen.acs.org/environment/persistent-pollutants/no-need-control-PFAS-as-class-industry-scientists-say/99/i19"><i>There’s no need to control PFAS as a class, industry scientists say.</i></a> In: <i><a href="Chemical_%26_Engineering_News" title="Chemical & Engineering News">Chemical & Engineering News</a>.</i> 19. Mai 2021,<span class="Abrufdatum"> abgerufen am 10. April 2022</span>.</span><span style="display: none;" class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Adc&rfr_id=info%3Asid%2Fde.wikipedia.org%3APerfluoroctan&rft.title=There%E2%80%99s+no+need+to+control+PFAS+as+a+class%2C+industry+scientists+say&rft.description=There%E2%80%99s+no+need+to+control+PFAS+as+a+class%2C+industry+scientists+say&rft.identifier=https%3A%2F%2Fcen.acs.org%2Fenvironment%2Fpersistent-pollutants%2Fno-need-control-PFAS-as-class-industry-scientists-say%2F99%2Fi19&rft.date=2021-05-19"> </span></span>
</li>
<li id="cite_note-7"><span class="mw-cite-backlink"><a href="#cite_ref-7">↑</a></span> <span class="reference-text"><cite style="font-style:italic">Toward a New Comprehensive Global Database of Per- and Polyfluoroalkyl Substances (PFASs): Summary Report on Updating the OECD 2007 List of Per- and Polyfluoroalkyl Substances (PFASs)</cite> (= <cite style="font-style:italic">OECD Series on Risk Management of Chemicals</cite>. <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em"> </span>39</span>). <a href="OECD" class="mw-redirect" title="OECD">OECD</a>, 2018, ISBN 978-92-64-88443-4, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1787/1a14ad6c-en">10.1787/1a14ad6c-en</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rfr_id=info:sid/de.wikipedia.org:Perfluoroctan&rft.btitle=Toward+a+New+Comprehensive+Global+Database+of+Per-+and+Polyfluoroalkyl+Substances+%28PFASs%29%3A+Summary+Report+on+Updating+the+OECD+2007+List+of+Per-+and+Polyfluoroalkyl+Substances+%28PFASs%29&rft.date=2018&rft.doi=10.1787%2F1a14ad6c-en&rft.genre=book&rft.isbn=9789264884434&rft.pub=OECD&rft.series=OECD+Series+on+Risk+Management+of+Chemicals" style="display:none"> </span></span>
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<li id="cite_note-8"><span class="mw-cite-backlink"><a href="#cite_ref-8">↑</a></span> <span class="reference-text">Alexander Schütz, Sebastian Brandt, Sascha Liedtke, Daniel Foest, Ulrich Marggraf, Joachim Franzke: <cite style="font-style:italic">Dielectric Barrier Discharge Ionization of Perfluorinated Compounds</cite>. In: <cite style="font-style:italic"><a href="Analytical_Chemistry" title="Analytical Chemistry">Analytical Chemistry</a></cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em"> </span>87</span>, <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em"> </span>22</span>, 2015, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>11415–11419</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1021/acs.analchem.5b03538">10.1021/acs.analchem.5b03538</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rfr_id=info:sid/de.wikipedia.org:Perfluoroctan&rft.atitle=Dielectric+Barrier+Discharge+Ionization+of+Perfluorinated+Compounds&rft.au=Alexander+Sch%C3%BCtz%2C+Sebastian+Brandt%2C+Sascha+Liedtke%2C+...&rft.date=2015&rft.doi=10.1021%2Facs.analchem.5b03538&rft.genre=journal&rft.issue=22&rft.jtitle=Analytical+Chemistry&rft.pages=11415-11419&rft.volume=87" style="display:none"> </span></span>
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